Mechanical and erosion properties of CaCO3‐EMAA thermal sprayed coatings

Polymer‐ceramic composite coatings manufactured from calcium carbonate and ethylene‐methacrylic acid copolymer (EMAA) were prepared via a thermal spray process employing different CaCO₃ filler sizes (average size of 2.8, 9 or 36 μm) and loading levels from about 2.5 to 7 wt%. The optimum filler feeding characteristics, deposition efficiency and deposition rate were obtained with a 36 μm sized CaCO₃. Tensile properties, peel strength, and the erosion resistance of a pure EMAA and CaCO₃‐EMAA composite coatings were investigated. It was found that the tensile strain at fracture of the composite coating decreased with the addition of filler to a greater degree than that observed in compression‐molded polymer composites. This is attributed to an inhomogenous distribution of the filler, with more being concentrated at the boundaries of the deposited polymer particles, thereby establishing a rigid framework within the coating. Only a small filler content is necessary to establish large changes in the mechanical properties of the coating. The peel strength of a composite coating decreases with filler content, both on a mild steel substrate and a previously sprayed polymer coating. Bonding to the latter is significantly higher and offers a possibility as a bonding layer between substrates and composite coatings. The coefficient of friction is lowered with the addition of a filler. Erosion testing has shown that the erosion resistance of PF111 is little improved overall with filler addition, although some increase is found for filler contents less than 5 vol%. Polym. Eng. Sci. 44:1448–1459, 2004. © 2004 Society of Plastics Engineers.     

Context dependence of phenotype prediction and diversity in combinatorial mutagenesis

Two different combinatorial mutagenesis experiments on the light-harvestingII (LH2) protein of Rhodobacter capsulatus indicate that heuristicrules relating sequence directly to phenotype are dependenton which sets or groups of residues are mutated simultaneously.Previously reported combinatorial mutagenesis of this chromogenicprotein (based on both phylogenetic and structural models) showedthat substituting amino acids with large molar volumes at Gly^ß31caused the mutated protein to have a spectrum characteristicof light-harvesting I (LH1). The six residues that underwentcombinatorial mutagenesis were modeled to lie on one side ofa transmembrane -helix that binds bacteriochlorophyll. In asecond experiment described here, we have not used structuralmodels or phylogeny in choosing mutagenesis sites. Instead,a set of six contiguous residues was selected for combinatorialmutagenesis. In this latter experiment, the residue substitutedat Gly^ß31 was not a determining factor in whetherLH2 or LH1 spectra were obtained; therefore, we conclude thatthe heuristic rules for phenotype prediction are context dependent.While phenotype prediction is context dependent, the abilityto identify elements of primary structure causing phenotypediversity appears not to be. This strengthens the argument forperforming combinatorial mutagenesis with an arbitrary groupingof residues if structural models are unavailable.     

Assessment of a redox alkaline/iron-chelate absorption process for the removal of dilute hydrogen sulfide in air emissions

The oxidative absorption of hydrogen sulfide (H₂S) into a solution of ferric chelate of trans-1,2- diaminocyclohexanetetraacetate (CDTA) was studied in a counter-current laboratory column randomly packed with 15 mm plastic Ralu rings. The present investigation takes concern about the Kraft pulping situation where dilute H₂S concentrations are omnipresent in large-volume gas effluents. A fractional two-level factorial approach was instigated to determine the significance of six operating variables, namely the solution's alkalinity (pH; 8.5-10.5), the liquid mass flow rate (L;1.73-), the solution's ionic strength (I_C;0.01-), the gas mass flow rate (G;0.19-), the inlet H₂S concentration (C_H2S,0;70-430 ppm) and the initial ferric CDTA concentration (C_Fe,0;100 -). Initially, a Plackett-Burman design matrix of seven duplicated experiments revealed that pH is the leading factor controlling the H₂S conversion rate while the ionic strength and ferric CDTA concentration effects remained negligible within the factorial domain. Surface response analysis based on 11 duplicated factorial experiments plus 10 central composite trials revealed that the H₂S conversion significantly increases with liquid flow rate but decreases with growing H₂S load up. Further examination about the influence of ferric CDTA on H₂S absorption rate was set up over a broader concentration range (C_Fe,0;0- at pH of 9.5 and 10.5. It showed good potential at as H₂S conversion increased by a significant 25% for both pH values in comparison to pure alkaline solutions containing no ferric CDTA.     

Molecular aspects of the transport and toxicity of ochratoxin a

Ochratoxins are a class of naturally occurring compounds produced by several fungi. The most toxic is ochratoxin A (OTA), and occurrence of some human nephropathies and tumors correlate with enhanced OTA exposure. In this Account, the following areas are examined: molecular details of the binding of OTA to human serum albumin (HSA), the influences of binding to HSA on the trans-port of OTA across epithelial cell membranes by organic anion transport proteins, the oxidative activation of OTA, and the formation of OTA adducts with biological molecules. These studies are beginning to provide a detailed chemical model for the trans-port, accumulation, and genotoxic and carcinogenic effects of OTA.     

Der Sicherheitsaspekt beim Eintrag von Schüttgütern in Behälter

Safety aspects of charging bulk material into vessels or containers . The safe charging of bulk material requires a careful analysis of the potential sources of danger which can result from the physical properties of the materials and the design and construction material of plant and equipment. The method adopted in this analysis is illustrated and explained for selected examples. Criteria for safe charging methods are compiled and explained. A selection of proven charging equipment is listed and technically evaluated with respect to safety and operating criteria. Steps that must be taken to avoid charging errors are discussed. Special problems encountered on connecting pressureless charging devices to pressure vessels are outlined explained. The utilization of inert gas as a preferred method of explosion protection is discussed. Various methods are compared, and their application to special problems in charging bulk material is illustrated.     

In vivo and in vitro lipid accumulation inBorago officinalis L.

Seeds of 13 accessions of borage (Borago officinalis) varied in total fatty acid content from 28.6 to 35.1% seed weight, with linoleic, γ-linolenic, oleic and palmitic as the predominant fatty acids, averaging 38.1%, 22.8%, 16.3% and 11.3% of total fatty acids, respectively. There was an inverse relation between γ-linolenic acid (25.0 to 17.6%) and oleic acid (14.5 to 21.3%). Fatty acid content of leaf tissues was 9.1% dry weight, with α-linolenic acid 55.2% and γ-linolenic acid 4.4% of total fatty acids. Cotyledons were the major source of fatty acids in seeds. Seed fatty acid content increased from <1 mg at six days postanthesis to about seven mg at maturity (22 to 24 days). Individual fatty acid content of seed was relatively constant after day 8. When immature embryos from 6 to 16 days postanthesis were cultured in a liquid or semisolid basal medium, fatty acid composition was similar to that of in vivo-grown seeds. Growth of cultured embryos decreased as sucrose concentration was increased from 3 to 20% in the basal medium, and most embryos did not survive 30% sucrose; fatty acid as a percentage of dry weight was maximal at 6% sucrose.     

What to do after a data breach? Examining apology and compensation as response strategies for health service providers

Innovative IT-enabled health services promise tremendous benefits for customers and service providers alike. Simultaneously, health services by nature process sensitive customer information, and data breaches have become an everyday phenomenon. The challenge that health service providers face is to find effective recovery strategies after data breaches to retain customer trust and loyalty. We theorize and investigate how two widely applied recovery actions (namely apology and compensation) affect customer reactions after a data breach in the specific context of fitness trackers. Drawing on expectation confirmation theory, we argue that the recovery actions derived from practice, apology, and compensation address the assimilation-contrast model’s tolerance range and, thus, always lead to satisfaction with the recovery strategy, which positively influences customers’ behavior. We employ an experimental investigation and collect data from fitness tracker users during a running event. In the end, we found substantial support for our research model. Health service providers should determine specific customer expectations and align their data breach recovery strategies accordingly.

     

GPU-based parallel Shadow Features generation at neural system for improving gait human activity recognition

Multimedia Tools and Applications - In this paper, we propose a new method for improving human activity recognition (HAR) datasets in order to increase their classification accuracy when trained...     

Consumer‐diet discrimination of δ13C and δ15N: Source‐ and feeding‐oriented patterns based on gut content analysis in a large subtropical river of China

Understanding the trophic discrimination (?¹³C and ?¹⁵N) between consumers and diets in fluvial systems remains difficult because of the variable food sources and complex predator–prey interactions from headwaters to the estuaries. Here, stable carbon (δ¹³C) and nitrogen (δ¹⁵N) isotopes in fish and invertebrates from a large subtropical river in southern China were determined to explore trophic discrimination in conjunction with a gut content analysis. The ?¹³C values showed significant differences (p < .05) among functional feeding groups, with fish, shrimp, and insect scrapers presenting higher ?¹³C values (1.20 ± 0.23‰ to 1.51 ± 0.31‰) than other groups. The ?¹⁵N values varied significantly between invertebrates (0.64 ± 0.17‰ of insect collector‐gatherers to 1.63 ± 0.36‰ of shrimp predators) and fish (1.98 ± 0.19‰ of detritivores to 2.71 ± 0.43‰ of crustaceavores) and exhibited an increasing tendency from primary to secondary consumers. A linear regression analysis revealed that the longitudinal changes in ?¹³C and ?¹⁵N were closely associated with the δ¹³C of periphyton, the δ¹⁵N of particulate organic matter (POM) in water, and the relative contribution (%) of periphyton and organic detritus to the diet composition of consumers. These results indicated that discrimination factors might not only be influenced by the isotope signatures of basal food sources but also downstream shifts in dominant food items utilized by consumers. In particular, trophic discrimination between periphyton– and detritus–based food chains, such as “epilithic diatoms–shrimp scrapers–crustaceavorous fish” and “POM–bivalves–molluscivorous fish,” displayed regionally specific patterns. When back‐calculating to the diet assimilation and trophic position in subtropical streams and rivers, we suggest using the basin‐scale ?¹³C value of 0.96 ± 0.26‰ for all consumers and ?¹⁵N values of 1.07 ± 0.32‰ for invertebrates and 2.38 ± 0.37‰ for fish.     

Relationship between microstructure and mechanical properties of polyether block amide foams

The mechanical behaviors of five polyether block amide foams, obtained by mold-opening foam injection process, were investigated with regard to their microstructures. The materials vary in mass ratios of hard versus soft segments, and/or in process packing time. The resulting microstructures have been characterized in terms of cavity size and shape ratios, by analyzing scanning electron microscope images after careful sample preparation. The foam mechanical responses have been characterized in compression at small and large strain. At small strain, the initial linear part of the stress–strain curve is enhanced firstly by the hard segment mass ratio and secondly by the fineness of the microstructure. Similar results have been obtained at large strain. The foam viscoelasticity at large strain has been characterized by stress relaxation and strain recovery tests, relevant for foam applications. Reduced packing time and pressure have been shown to lead to the presence of undesired large cavities. The morphological defects appear to have a negligible impact on the macroscopic mechanical behavior of the foams at infinitesimal strain, but lead to critical inconsistency at large strain. Furthermore, the mechanical behavior of the tested polyether block amide foams is controlled first by hard versus soft segments ratio, and second by the microstructure fineness.